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D5: XX023X and D2: XX0230, or you can play a regular D major 
and it sounds fine.  The D5 and D2 reflect the accented notes that
(I think) a second guitar plays.  I've tried to explain this at 
the bottom.  If you don't want to go to all that hassle, just strum
a D chord and occasionally lift your finger off the e-string.

A E D5 D2 x2

A (x02220@1)   E (022100@1)    D5 (xx023x@1)            D2 (x43141@2) Sin city      Please don't take
A (x02220@1)          E (022100@1)        D5 (xx023x@1)      D2 (x43141@2) My lover's heart, for mine will break
A (x02220@1)       E (022100@1)        D5 (xx023x@1)            D2 (x43141@2) It's no Pittsburg     Please don't go
A (x02220@1)E (022100@1) D5 (xx023x@1)D2O--hi--o (x43141@2)
A E D5 D2 x2
 
A (x02220@1)              E (022100@1)            D5 (xx023x@1)     D2 (x43141@2) You can take a tug there, oh,   take a train
A (x02220@1)      E (022100@1)    D5 (xx023x@1)     D2 (x43141@2)    
  Either way, I ain't going
A (x02220@1)       E (022100@1)        D5 (xx023x@1)            D2 (x43141@2) It's no Pittsburg     Please don't go
A (x02220@1)E (022100@1) D5 (xx023x@1)name="chord_x43141@2">D2  DO--hi--o (xx0232@1)
G (320003@1)                                D (xx0232@1) And I could see her lying in the valley
     ADown (x02220@1)below
G (320003@1)                                   D (xx0232@1) And I could smell the green of those hills
               EThose (022100@1)Kentucky hills

A (x02220@1)              E (022100@1)            D5 (xx023x@1)     D2 (x43141@2) You can take a tug there, oh,   take a train
A (x02220@1)      E (022100@1)    D5 (xx023x@1)     D2 (x43141@2)    
  Either way, I ain't going
A (x02220@1)       E (022100@1)        D5 (xx023x@1)            D2 (x43141@2) It's no Pittsburg     Please don't go
A (x02220@1)E (022100@1) D5 (xx023x@1)name="chord_x43141@2">D2 
O--hi--o

A E D5 D2 repeat


Notes:
Here's how I play the chords with one guitar and sound
reasonably like the recording.  Pluck the notes under the 
^ symbol, strum down , strum up /.

 A (x02220@1)        E (022100@1)        D5 (xx023x@1)       D2 (x43141@2)^   / /  ^   / /  ^   / / ^ ^   / / 
-0--------0-0--------0----------2-0--------0------|
----2-2-2-2----0-0-0-0-3--3-3-3------3-3-3-3------|
----2-2-2-2----1-1-1-1----2-2-2------2-2-2-2------|
-2--2-2-2---2--2-2-2---0--0-0-0-0-0--0-0-0--------|
--------------------------------------------------|
--------------------------------------------------|

 ^   / /  ^   / /  ^   / /  ^   / / 
-0--------0-0--------0---------------0-----0------|
----2-2-2-2----0-0-0-0-3--3-3-3-3-3--3-3-3-3------|
----2-2-2-2----1-1-1-1----2-2-2-2-2--2-2-2-2------|
-2--2-2-2---2--2-2-2---0--0-0-0-0-0--0-0-0--------|
--------------------------------------------------|
--------------------------------------------------|

This is the riff played at the end
---7---5-7----------|
-(7)-8-----8--------|
--------------------|
--------------------|
--------------------|
--------------------|



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