Country music is my dirty little secret. Unfortunately I'm not much of a guitar player 
:(. Having said that I managed to piece together the very simple chords to this lovely 
little song. It's my first attempt at chord notes so they may not be perfect. Enjoy anyway.
Also, watch out for the alternative G chords, and try flipping between D and Dsus7 for 
that new country feel :).

Capo on 2nd fret

Chords used (in the form EADGBE)
G (320003@1)     320033
G(alt)  320003
D (xx0232@1)     000232
A (x02220@1)     002220
Em7     022030

Intro:
G D x3
D G(alt)

[verse]
G (320003@1)          DIf (xx0232@1)you blink you might miss it
G (320003@1)          DPopulation (xx0232@1)803
G (320003@1)             DFive (xx0232@1)miles long, four miles wide
G(alt)
Feels just right to me
G (320003@1)                      DWhere (xx0232@1)a handshake still means something
G (320003@1)                      DAnd (xx0232@1)the little man still counts
G (320003@1)                           DWhere (xx0232@1)the water tastes like it's supposed to
G(alt)
Yeah, folks around here are proud
G (320003@1)      A (x02220@1)     DTo (xx0232@1)be from Little Town

[Chorus]
A (x02220@1)                           Em7
Well the stars they just seem brighter
A (x02220@1)                      G(alt)
And the pace is nice and slow
A (x02220@1)               DAnd (xx0232@1)families stay together
    D (xx0232@1)     A (x02220@1)     G (320003@1)  G (320003@1)     A (x02220@1)    DGod (xx0232@1)must be smiling down here on Little Town

D Dsus7 D

[Verse]
G (320003@1)                        DThere's (xx0232@1)a cardboard lemonade stand
G (320003@1)               DAt (xx0232@1)the end of our drive
G (320003@1)                 DFor (xx0232@1)50-cents they'll fill you up
G(alt)
He's seven and she's five
G (320003@1)                            DAnd (xx0232@1)in the fall there's football Fridays
G (320003@1)                    DWe (xx0232@1)pack the kids and we head out
G (320003@1)              DClimb (xx0232@1)the stands pass the band
G(alt)
And join the hometown crowd
G(alt)         A (x02220@1)    Dsus7  DAnd (xx0232@1)scream "Go Little Town"

Dsus7   D x2
G (320003@1)name="chord_320003@1">G       A (x02220@1)  D[Repeat (xx0232@1)Chorus]

D (xx0232@1)                A (x02220@1)     G (320003@1)  G (320003@1)     A (x02220@1) 
   DArent' (xx0232@1)you glad we settled down here in Little Town

G (320003@1)          DIf (xx0232@1)you blink you might miss it
G (320003@1)          DPopulation (xx0232@1)803
G (320003@1)             DFive (xx0232@1)miles long, four miles wide
G(alt)
Feels just right to me