Hope this is correct, sounds good to me for a simple tab. Listen to song for the rhythm 
and timing.
I had help from a tutorial video and the live Eisley acoustic video.
Ptblood has a good tutorial and cover but I changed a few chords after watching Eisley 
perform it.
Suggestions welcome!

My cover of The Valley -- http://www.youtube.com/watch?v=dd6rrpsJWu8
ptblood - The Valley Tutorial -- http://www.youtube.com/watch?v=Foc9z_TIJ20--|
Eisley - The Valley (Acoustic) -- http://www.youtube.com/watch?v=16_P9wAJ7LA-|

The Valley

Dm (xx0231@1)       Freal (133211@1)heart-breaker come and take me
       C (x32010@1)  C7 (x32310@1)  F (133211@1)                           Dmto (xx0231@1)the real heart ache that everyone's talking 'bout.
    Fyou (133211@1)see me then you don't
           C (x32010@1)   C7 (x32310@1) Fbut (133211@1)get it right, i don't believe in magic.

(Dm    F (133211@1)  CC7    F) x2
      some "oh"'s

Dm (xx0231@1)       Ffire (133211@1)kites drifting through the skies
      C (x32010@1) C7F
up on high i see it all the time
             Dm (xx0231@1)       Fand (133211@1)from the tip top of every mountain view
         C (x32010@1) C7F
from the roof i spy on room to room.

Dm (xx0231@1)    Bbtake (x1333x@1)me home
  Bm (x24432@1)                   Ci (x32010@1)walk the night in the valley
D (xx0232@1)    Bboh (x1333x@1)ohh oh
Bm (x24432@1)               D5'til (xx023x@1)everything is fine

Dm (xx0231@1)           Fi (133211@1)walked all night, and typically that's fine
      C (x32010@1)   C7 (x32310@1)Fbut (133211@1)i might try sleeping for a bit.
        Dm (xx0231@1)    Ftell (133211@1)me why you know the things you do
              Cand (x32010@1)how'd you get there?
   C7 (x32310@1)      Fto (133211@1)be there, it must be great for you.

Dm (xx0231@1)    Bbtake (x1333x@1)me home
  Bm (x24432@1)                  Ci (x32010@1)walk the night in the valley
D (xx0232@1)    Bmoh (x24432@1)ohh oh
Bb (x1333x@1)               D5'til (xx023x@1)everything is fine [x2]

D (xx0232@1)                       Bmi (x24432@1)don't see everything as right
         Ait's (x02220@1)not right
G (320003@1)                       Em (022000@1)      Bmi (x24432@1)don't see everything as right and wrong
     Ait's (x02220@1)so wrong
Gbut (320003@1)i don't see everything as wrong

Dm (xx0231@1)    Bbtake (x1333x@1)me home
Bm (x24432@1)                    Ci (x32010@1)walk the night in the valley
D (xx0232@1)    Bmoh (x24432@1)ohh oh
Bb (x1333x@1)               D5'til (xx023x@1)everything is fine

Dm (xx0231@1)    Bbtake (x1333x@1)me home
Bm (x24432@1)                    Ci (x32010@1)walk the night in the valley
D (xx0232@1)    Bmoh (x24432@1)ohh oh
Bb (x1333x@1)               D5'til (xx023x@1)everything is fine

Bb (x1333x@1)               D5'til (xx023x@1)everything is fine
Bb (x1333x@1)               D5'til (xx023x@1)everything is fine
G (320003@1)                D5'til (xx023x@1)everything is fine
Bb (x1333x@1)               D5'til (xx023x@1)everything is fine