The intro is the 'hendrix chord' but on the 5th fret then the 6th

D7#9 then Eflat7#9

D7#9     Eflat7#9   
Ex (022100@1)     x  
B6 (x2444x@1)     7
G5 (320003@1)     6
D4 (xx0232@1)     5
A5 (x02220@1)     6
Ex (022100@1)     x

Sorry I dont know how to draw the flat sign on here!
Play the C and E flat as bar chords on the 8th and 6th

Intro
D7#9 Eflat7#9 repeat x4

Verse
C (x32010@1)                             Eflat
Van Tango had a mean old scene, Van Tango!
(Mean old scene, Van Tango)
C (x32010@1)                              Eflat
Van Tango had a mean old scene, Van Tango!
(Mean old scene, Van Tango)
C (x32010@1)                           Eflat 
He worked night-shift at the opera
(Mean old scene, Van Tango)
C (x32010@1)                     Eflat 
Watching the girls go by
(Girls go by, Van Tango)
C (x32010@1)                 Eflat
He's singled out tonight
(Singled out, Van Tango)
C (x32010@1)                    repeat intro from here
He's singled out every night
(Singled out, Van Tango) 

The rest should be obvious!