This will be A*
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here we go:
                    A*
Cause it's the pick
     C
Of destiny, child
     F
You know it will be rocking
             G
cause it's fuckin' insane!

                   A*
It's just the pick
    C
Of destiny, child
      F
More precious than a diamond
        G
on a platinum chain

Am
  In Venice Beach
             C
there was a man named Kage
F
  When he was buskin'
       G
He was outta the rage

Am
  He met Jables
         C
And it taught him well
F
  All the techniques
            G
that were developed in hell

Am
  Cock push-ups
         C
and the power-slide
F
  Gig-Simulation,
            G
now there's no where to hide

Am
  They formed a band
              C
they named Tenacious D
F
  and then they got
            G
the Pick of Destiny

                    A*
Cause it's the Pick
   C
of Destiny, child
     F
you know it will be rockin'
            G
cause it's fuckin' insane

                 A*
This is the Pick
   C
of Destiny, child
    F
Our tasty grooves are better
        G
than a Chicken ChowMein

      F
Cause he, who is sleezy
    G
Is easy to pleasy
     F
And she, who is juicy
     G
Must be Lucy Goosey
    F
And he who is groovy
     G
Will be in my movie, so come on!

(interlude: Am, C, F, Dm, Em, Em, Em, Em)

    Dm
The wizard and the demon
       
had a Battle Royale
     Am
The demon almost killed him

with a Needle-Ka-Pow!
    C
But then he broke his tooth
              G
and thus the demon said "ow!"

                   A*
Cause it's the Pick
    C
of Destiny, child
     F
You know it will be rockin'
            G
cause it's fuckin' insane

                  A*
It's just the Pick
    C
of Destiny, child
     F
You know our movie's better
          G
than the Citizen Kane

      F
Cause he, who's a geezer
      G
Must live in my freezer
     F
And she, who is starky
    G
Is full of milarky
    F
And he, who is groovy
     G
Must be in my movie so come on

           F
Oh, cause if you're a diva
     G
Then go to Geneva
    F
And if you're a croney
      G
Then suck on my boney
     F
And if you are groovy
      G
Then get in my movie,

It's called
    Am   Am G  G Am
The Pick of Destiny!
    Dm   Am Em C Am
The Pick of Destiny...

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Should be about right ^^
Have fun