To see the riff, go to "Black Leather Woman (intro)" on this page.  But here are the chords....

(E?) She's a black leather woman
She was never good no how (intro riff)
She's a black leather woman
She was never good no how (intro riff)
(F#)She used to live with her mama
Yes but that's all over now (intro riff)

(E?) She's got the black boots and buckles
And her own black motor bike (intro riff)
She's got the black boots and buckles
And a cut-down motor bike (intro riff)
(F#)She used to live with her mama
But now she lives anywhere she likes

B-, B- (A in base), B- (G in base) F# (intro riff)

(E?) Oh shes a black leather woman
You cant control her now
Shes a black leather woman
You cant control her now
(F#) She used to live with her mama
Yes but thats all over now

B-, B- (A in base), B- (G in base) F# end on E?

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E?- 020100 

^ and sometimes u can add this to the E? chord to make it sound nice: 020130 (very Bob Dylan like)