Here is the tab for the main riff of "Black Leather Woman" as performed on the Tonight Show
Tabbed By Brandon Pace


Scott plays this riff
Just finger pick the open B string with each note.
e---------------------------------------------
b-0-0-0-0-0-0-0-0-0-0-0---0-0-0-0-0-0-0-0-0-0-
g---------------------------------------------
d---0-2-3-3-3-2-2-2-0-------0-2-3-3-3-2-2-0---
a-2------------------2-2--2-----------------0-
e---------------------------------------------

Tom Plays this riff
e-----------------------------
b-----------------------------
g-----------------------------
d-----------------------------
a---7-9-10-10-10-9-9-9-7------
e-9----------------------9-9--

Main Chords for the Verse are E & D power Chords