Song: To Be The One
Artist: Ryan Adams
Album: Heartbreaker
Tuning: Standard (Capo on 3rd, so the G C and D are actually Ab Eb and Db)

Intro: (one |...| represents one beat) so it's like this:

1   2   3   4and  1   2   3   4and
G| (320003@1)G| (320003@1)G| (320003@1)GC | G| (320003@1)G| (320003@1)G| (320003@1)GC | 

And he just picks the chords lightly, and plays harmonica on top of it.
The rest of the song goes like this:

         G (320003@1)                          CWell (x32010@1)the pills I got they ask me lets go out for a while
        G (320003@1)                                 CAnd (x32010@1)the knives up in the kitchen are all too dull to smile
             GYeah (320003@1)and the sun it tries to warn me
         CBoy (x32010@1)those wings are made of wax
          C (x32010@1)            GWhile (320003@1)the things I do to kill me
            DThey (xx0232@1)just tell me to relax

       GBut (320003@1)oh... cinderella
                                              CAll (x32010@1)dressed up in all your boots and all your charms
            GI'm (320003@1)not the fellow
                                            DTo (xx0232@1)protect you or to keep you from all your harm
    G (320003@1)          C (x32010@1)       GAnd (320003@1)I don't know which is worse
               CTo (x32010@1)wake up and see the sun
      DOr (xx0232@1)to be the one be the one
       G (320003@1) C (x32010@1)     GBe (320003@1)the one that's gone

C (x32010@1)G (320003@1)
(he kind of starts strumming here, but still light)

        G (320003@1)              C (x32010@1)   GAnd (320003@1)the empty bottle it misses you
         G (320003@1)                   C (x32010@1)          GYeah (320003@1)and I'm the one that it's talking to
         G (320003@1)                   C (x32010@1)       GAnd (320003@1)with you and I just barely strangers
      DI'm (xx0232@1)pretty much just left the fool
     GDamn... (320003@1)don't the streets look empty though
       CJust (x32010@1)wandering round here without you

       C (x32010@1)             G (320003@1)                    C (x32010@1)              GOh (320003@1)the empty bottle it misses you and I'm the one it's talking to

C G C G

    G (320003@1)          C (x32010@1)       GAnd (320003@1)I don't know which is worse
               CTo (x32010@1)wake up and see the sun
      DOr (xx0232@1)to be the one be the one
       G (320003@1) C (x32010@1)    Gbe (320003@1)the one that's gone

CG CG 

End on G

Cheers, Max