The intro is the 'hendrix chord' but on the 5th fret then the 6th

D7#9 then Eflat7#9

D7#9     Eflat7#9   
E x      x  
B 6      7
G 5      6
D 4      5
A 5      6
E x      x

Sorry I dont know how to draw the flat sign on here!
Play the C and E flat as bar chords on the 8th and 6th

Intro
D7#9 Eflat7#9 repeat x4

Verse
C                               Eflat
Van Tango had a mean old scene, Van Tango!
(Mean old scene, Van Tango)
C                                Eflat
Van Tango had a mean old scene, Van Tango!
(Mean old scene, Van Tango)
C                             Eflat 
He worked night-shift at the opera
(Mean old scene, Van Tango)
C                       Eflat 
Watching the girls go by
(Girls go by, Van Tango)
C                   Eflat
He's singled out tonight
(Singled out, Van Tango)
C                      repeat intro from here
He's singled out every night
(Singled out, Van Tango) 

The rest should be obvious!