This will be A*
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here we go:
                    A*
Cause it's the pick
     COf (x32010@1)destiny, child
     FYou (133211@1)know it will be rocking
             Gcause (320003@1)it's fuckin' insane!

                   A*
It's just the pick
    COf (x32010@1)destiny, child
      FMore (133211@1)precious than a diamond
        Gon (320003@1)a platinum chain

Am (x02210@1) In Venice Beach
             Cthere (x32010@1)was a man named Kage
F (133211@1) When he was buskin'
       GHe (320003@1)was outta the rage

Am (x02210@1) He met Jables
         CAnd (x32010@1)it taught him well
F (133211@1) All the techniques
            Gthat (320003@1)were developed in hell

Am (x02210@1) Cock push-ups
         Cand (x32010@1)the power-slide
F (133211@1) Gig-Simulation,
            Gnow (320003@1)there's no where to hide

Am (x02210@1) They formed a band
              Cthey (x32010@1)named Tenacious D
F (133211@1) and then they got
            Gthe (320003@1)Pick of Destiny

                    A*
Cause it's the Pick
   Cof (x32010@1)Destiny, child
     Fyou (133211@1)know it will be rockin'
            Gcause (320003@1)it's fuckin' insane

                 A*
This is the Pick
   Cof (x32010@1)Destiny, child
    FOur (133211@1)tasty grooves are better
        Gthan (320003@1)a Chicken ChowMein

      FCause (133211@1)he, who is sleezy
    GIs (320003@1)easy to pleasy
     FAnd (133211@1)she, who is juicy
     GMust (320003@1)be Lucy Goosey
    FAnd (133211@1)he who is groovy
     GWill (320003@1)be in my movie, so come on!

(interlude: Am, C, F, Dm, Em, Em, Em, Em)

    DmThe (xx0231@1)wizard and the demon
       
had a Battle Royale
     AmThe (x02210@1)demon almost killed him

with a Needle-Ka-Pow!
    CBut (x32010@1)then he broke his tooth
              Gand (320003@1)thus the demon said "ow!"

                   A*
Cause it's the Pick
    Cof (x32010@1)Destiny, child
     FYou (133211@1)know it will be rockin'
            Gcause (320003@1)it's fuckin' insane

                  A*
It's just the Pick
    Cof (x32010@1)Destiny, child
     FYou (133211@1)know our movie's better
          Gthan (320003@1)the Citizen Kane

      FCause (133211@1)he, who's a geezer
      GMust (320003@1)live in my freezer
     FAnd (133211@1)she, who is starky
    GIs (320003@1)full of milarky
    FAnd (133211@1)he, who is groovy
     GMust (320003@1)be in my movie so come on

           FOh, (133211@1)cause if you're a diva
     GThen (320003@1)go to Geneva
    FAnd (133211@1)if you're a croney
      GThen (320003@1)suck on my boney
     FAnd (133211@1)if you are groovy
      GThen (320003@1)get in my movie,

It's called
    Am (x02210@1) Am (x02210@1)name="chord_320003@1">G  G (320003@1)name="chord_x02210@1">Am
The Pick of Destiny!
    Dm (xx0231@1) Am (x02210@1)name="chord_022000@1">Em C (x32010@1)name="chord_x02210@1">Am
The Pick of Destiny...

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Should be about right ^^
Have fun